Bis[N,N-bis(1-allyl-1H-benzimidazol-2-ylmethyl-κN 3)benzylamine-κN]cadmium dipicrate
نویسندگان
چکیده
The crystal structure of the title compound, [Cd(C(29)H(29)N(5))(2)](C(6)H(2)N(3)O(7))(2), consists of Cd(II) complex cations and picrate anions. In the complex cation, the Cd(II) ion is chelated by two bis-(1-allyl-benzimidazol-2-ylmeth-yl)benzyl-amine (babb) ligands in a distorted octa-hedral geometry. Extensive C-H⋯O hydrogen bonding occurs between cations and anions in the crystal structure.
منابع مشابه
Bis[2,6-bis(1-methyl-1H-benzimidazol-2-yl-κN 3)pyridine-κN]zinc dipicrate methanol disolvate
In the title compound, [Zn(C(21)H(17)N(5))(2)](C(6)H(2)N(3)O(7))(2)·2CH(3)OH, the Zn(II) atom is coordinated by six N atoms from two tridentate 2,6-bis-(1-methyl-1H-benzimidazol-2-yl)pyridine ligands in a distorted octa-hedral environment. In the crystal, the picrate anions and methanol solvent mol-ecules are connected by O-H⋯O hydrogen bonds. Weak inter-molecular C-H⋯O hydrogen bonds are also ...
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متن کامل{2-[6-(1H-Benzimidazol-2-yl-κN 3)-2-pyridyl-κN]benzimidazolato-κN}(dicyanamido-κN)(methanol-κO)copper(II)
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011